Name:  ______________________________            period 6                             date:  _______

Ch. 21 & 14  Nuclear chem. & kinetics  test             [70 points]                   AP  Chemistry

For problems involving calculations, show the relevant equation (or formula and conversion factor(s)), show your work in an organized manner, put the proper units in your calculations / answer, and have the proper number of significant figures in your answer.

Academic Honesty:   The answers on this test are my own and I am using only the allowed set of notes as described in the syllabus.  I have not discussed the test questions with anyone before or during the test nor have I seen the test questions prior to the exam.  If you violate any of the preceding items or do not sign, your semester grade is a F.

Signature:  ___________________

1.  write the (hypothetical ?) nuclear reaction for __.  [15 points]

a.  alpha decay of 210 Pb:  ____________________________

b.  beta-decay of 32 P:  _______________________________

c.  positron emission of 29 Al:  _________________________

d.  nuclear fusion involving 4 He & 15 N (as reactants) form:  ______

e.  240 U  ->  3 neutrons  +  140 Ba  +  _____

2.  14 C has a half-life of 5.73 * 103 years.  A sample currently has 15 mCi 14C, but originally had 85 mCi 14 C; Ci = 3.7 * 1010 disintegrations / second.  What is the age of the sample ?  [10 points]

3.  If the rate of combustion of ethane is  - 5.0 mM / second, then what is the  [20 points]

a.    rate of appearance of carbon dioxide ?

b.  rate of appearance of water ?

c.  rate of disappearance of oxygen ?

d.  rate of the reaction ?

4.  Based on the following (hypothetical ?) experimental data,

 Expt [N2 ]  (M) [H2 ]  (M) (mM / sec) 1 1.0 1.0 1.0 2 1.0 2.0 2.0 3 2.0 1.0 4.0

for the reaction:  N2   +  H2   ->  NH3 , what is the rate law of the reaction (include the value of the exponents & rate constant, including its units)    [15 points]

5.  The ΔHreaction = - 35 kJ / mole;  Ea, backward = 15 kJ / mole.   [10 points]

a.  sketch and label the reaction energy profile

b.  calculate Ea, forward